Science and Technology of Advanced Materials (Dec 2017)

A new method to determine the un-poled elastic properties of ferroelectric materials

  • Chris. R. Bowen,
  • Andrew C. Dent,
  • Ron Stevens,
  • Markys G. Cain,
  • Andrew Avent

DOI
https://doi.org/10.1080/14686996.2017.1302274
Journal volume & issue
Vol. 18, no. 1
pp. 264 – 272

Abstract

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Piezoelectric devices with complex electrode geometries often contain ferroelectric regions that experience little or no electric field and remain unpolarised. Since the un-poled and poled material properties differ it is desirable to account for these regions in a device when developing predictive models or to design piezoelectric transducers. The lack of published data on the elastic properties for un-poled ferroelectrics, specifically the numerous commercial compositions such as lead zirconate titanate, reflects the difficulty of experimental measurement. In this work, a method for predicting un-poled properties from more commonly available poled data has been developed. A new method of calculating these properties is presented which provides a rapid and practical solution to the problem of evaluating the isotropic stiffness and Poisson’s ratio for an un-poled ferroelectric material. The way in which this calculation has been derived and validated is presented and detailed comparisons are made with alternative methods and experimental data.

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