Acta Crystallographica Section E (Dec 2008)

Poly[bis(μ-2,6-dimethylpyridinium-3,5-dicarboxylato-κ2O3:O5)copper(II)]

  • Guang-Feng Hou,
  • Bai-Yan Li,
  • Tao Jiang,
  • Yu-Hong Du,
  • Hong-Kun Zhang

DOI
https://doi.org/10.1107/S1600536808035873
Journal volume & issue
Vol. 64, no. 12
pp. m1510 – m1510

Abstract

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In the title coordination polymer, [Cu(C9H8NO4)2]n, the Cu atom, located on a twofold rotation axis, is four coordinate in a distorted square-planar environment. Each 2,6-dimethylpyridinium-3,5-dicarboxylate anion bridges two Cu atoms, forming a two-dimensional coordination polymer. A three-dimensional supramolecular network is built from N—H...O hydrogen bonds involving the pyridinium NH and the carboxyl COO groups.