Crystal structure of a three-dimensional neodymium(III) coordination polymer, [Nd2(H2O)6(glutarato)(SO4)2]n

Abstract

A three-dimensional coordination polymer, poly[hexaaqua(μ4-glutarato)bis(μ3-sulfato)dineodymium(III)], [Nd2(glutarato)(SO4)2(H2O)6]n (glutarato2– = C5H6O42–), 1, consisting of cationic {Nd2(H2O)6(SO4)2}n2n+ layers linked by bridging glutarate ligands, was synthesized by the microwave-heating technique within few minutes. The crystal structure of 1 consists of two crystallographically independent TPRS-{NdIIIO9} (TPRS is tricapped trigonal–prismatic geometry) units that form an edge-sharing dinuclear cluster interconnected to neighbouring dimers by the μ3-SO42– anions, yielding a cationic two-dimensional {Nd2(H2O)6(SO4)2}n2n+ sheet. Adjacent cationic layers are then linked via the μ4-glutarato2– ligands into a three-dimensional coordination network. Strong O—H...O hydrogen bonds are the predominant interaction in the crystal structure.

Keywords

• crystal structure
• coordination polymer
• lanthanide
• glutarate