Novel Fluorinated Nitrogen-Rich Porous Organic Polymer for Efficient Removal of Perfluorooctanoic Acid from Water

Abstract

The mobility, durability, and widespread use of perfluorinated and polyfluoroalkyl substances (PFAS), notably perfluorooctanoic acid (PFOA), bring about serious contamination of many ground and surface waters. In this study, fluorine and amine-functionalized porous organic polymer (POP-4F) was designed and successfully synthesized as an adsorbent for PFOA removal in water. The characterization results showed that the synthesized material had an amorphous microporous structure, and the BET surface area was up to 479 m2 g−1. Its versatile adsorption property was evaluated by batch adsorption experiments using PFOA as a probe. The experiments show that the polymer was able to remove 98% of the PFOA in 5 min from water and then desorb within 3 min in methanol ([PFOA]0 = 1 mg L−1; [POP-4F] = 200 mg L−1). Specifically, the adsorption capacity of POP-4F is up to 107 mg g−1, according to the Langmuir fit. The rapid adsorption and desorption of PFOA by POP-4F offers the possibility of economical, environmentally friendly, and efficient treatment of real wastewater.

Keywords

• perfluoro octanoic acid
• porous organic polymer
• adsorption removal