Facile fabrication of ZnO nanoparticles via non-thermal plasma technique and their anti-corrosive effects on X60 API 5L steel in 1M HCl solution
Nourelhouda Bounedjar,
Mohammed Fouad Ferhat,
Chun Ouyang,
Mohamed Bououdina,
Ihab Shawish,
Rasha A. Abumousa,
Muhammad Humayun
Affiliations
Nourelhouda Bounedjar
Renewable Energy Development Unit in Arid Zones (UDERZA), University of El Oued, 39000, El Oued, Algeria; Department of Chemistry, Faculty of Exact Sciences, University of El Oued, B.P. 789, 39000, Algeria; Corresponding author. Renewable Energy Development Unit in Arid Zones (UDERZA), University of El Oued, 39000, El Oued, Algeria.
Mohammed Fouad Ferhat
Renewable Energy Development Unit in Arid Zones (UDERZA), University of El Oued, 39000, El Oued, Algeria; Laboratory of Sciences and Techniques of the Environment and Valuation, Ibn Badis-ּMostaganem University, Algeria; Department of Process Engineering, Faculty of Technology, University of El Oued, B.P. 789, 39000, Algeria
Chun Ouyang
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, 212003, Jiangsu Province, China
Mohamed Bououdina
Energy, Water and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh, 11586, Saudi Arabia
Ihab Shawish
Energy, Water and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh, 11586, Saudi Arabia
Rasha A. Abumousa
Energy, Water and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh, 11586, Saudi Arabia
Muhammad Humayun
Energy, Water and Environment Lab, College of Humanities and Sciences, Prince Sultan University, Riyadh, 11586, Saudi Arabia; Corresponding author.
This work aims to explore the efficiency of ZnO nanoparticles synthesized via the non-thermal gliding arc discharge-assisted plasma (NT-GAD) technique for inhibiting the corrosion of X60 API 5L steel in a 1M HCl environment. The XRD pattern revealed that the ZnO nanoparticles exhibit hexagonal wurtzite structure with average particle size of ∼24 nm. UV–visible spectroscopy analysis revealed an absorption peak centering at 365 nm, corresponding to an energy band gap of 3.29 eV. SEM and TEM analysis revealed that the nanoparticles exhibit an agglomerated and irregular morphology. The corrosion inhibition of ZnO NPs was investigated via the electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization tests (PDP), while varying both concentration and temperature. The results revealed that the increase in inhibitor concentration resulted in a higher activity at ambient temperature, with an optimal efficiency of 93 % at a concentration of 100 mg/L. However, the increase in temperature remarkably reduced the inhibition efficiency, suggesting a physisorption behavior of ZnO NPs onto the steel surface. AFM and FE-SEM analysis confirmed the formation of a protective layer on the X60 API 5L steel surface. This study emphasizes the significant potential of ZnO NPs synthesized via the NT-GAD assisted plasma technique as corrosion inhibitor for X60 API 5L carbon steel in 1M HCl corrosive media.
