Temperature-dependent conduction mechanism of NiO@Carbon@Polypyrrole nanomaterial with EMI shielding characteristics

Abstract

A simple hydrothermal technique and in-situ chemical oxidative polymerization of pyrrole monomer yield the functionalized NiO@C@PPy nanomaterial for electromagnetic shielding applications. The crystal structure, morphology, dielectric and electromagnetic shielding (EMI) performance in the X-band (8.2–12.4 GHz) is thoroughly studied. Impedance spectroscopy is utilized to study the electrical response of a NiO@C@PPy pellet. This study focuses on the modulations of relaxation time with frequency at different temperatures. In the NiO@C@PPy composite, a semiconductor-to-metal transition (SMT) is observed, at 328 K. The conduction mechanism of NiO@C@PPy is explained based on the carrier hopping transport model in Ni2+ and Ni3+ ions. It is evident from the activation energy value (Ea ≈ 0.32 eV) determined from impedance, conductivity, and dielectric data that the relaxation and conduction processes correspond to the same electro-active region. Using the variable range hopping (VRH) model localization length of the carrier is calculated to be 1.56 Å. The NiO@C@PPy sample demonstrated enhanced conductivity and low dielectric values which are vital in EMI shielding applications. Consequently, the electromagnetic interference shielding effectiveness is found to be 21.9 dB of NiO@C@PPy in the X-band frequency range. This composite material is a good candidate for high frequency shielding applications.

Keywords

• Conduction mechanism
• Impedance spectroscopy
• Dielectric constant
• Semiconducting to metallic transition
• EMI shielding