The Mechanical and Energy Release Performance of THV-Based Reactive Materials

Abstract

A polymer of tetrafluoroethylene, hexafluoropropylene, and vinylidene fluoride- (THV) based reactive materials (RMs) was designed to improve their density and energy release efficiency. The mechanical performances, fracture mechanisms, thermal behavior, energy release behavior, and reaction energy of four types of RMs (26.5% Al/73.5% PTFE, 5.29% Al/80% W/14.71% PTFE, 62% Hf/38% THV, 88% Hf/12% THV) were systematically researched by conducting compressive tests, scanning electron microscope (SEM), differential scanning calorimeter, thermogravimetric (DSC/TG) tests and ballistic experiments. The results show that the THV-based RMs have a unique strain softening effect, whereas the PTFE-based RMs have a remarkable strain strengthening effect, which is mainly caused by the different glass transition temperatures. Thermal analysis indicates that the THV-based RMs have more than one exothermic peak because of the complex component in THV. The energy release behavior of RMs is closely related to their mechanical properties, which could dominate the fragmentation behavior of materials. The introduction of tungsten (W) particles to PTFE RMs could not only enhance the density but also elevate the reaction threshold of RMs, whereas the reaction threshold of THV-based RMs is decreased when increasing Hf particles content. As such, under current conditions, the THV-based RMs (88% Hf/12% THV) with a high density of 7.83 g/cm3 are adapted to release a lot of energy in thin, confined spaces.

Keywords

• THV-based reactive materials
• mechanical performances
• thermal analysis
• reaction threshold
• energy release behavior