IUCrData (Aug 2018)

(2-{[2-(Dimethylamino)ethyl]iminomethyl}benzenethiolato-κ3N,N′,S)(4-methoxybenzenethiolato-κS)nickel(II)

  • Mackenzie J. Freige,
  • Nilmini K. Senaratne,
  • David M. Eichhorn

DOI
https://doi.org/10.1107/S2414314618011677
Journal volume & issue
Vol. 3, no. 8
p. x181167

Abstract

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In the title compound, [Ni(C11H15N2S)(C7H7OS)] or [Ni(NNImS)(4-OCH3PhS)] (NNImS = 2-{[2-(dimethylamino)ethyl]iminomethyl}benzenethiolato), the NiII cation is coordinated by a tridentate NNImS ligand and a monodentate thiolate ligand giving an N2S2 coordination set defining an almost square-planar environment. The Ni—Namine bond in the coordination plane is approximately 0.1 Å longer than the Ni—Nimine bond.

Keywords