Nanophotonics (Jan 2023)

Electrically switchable metallic polymer metasurface device with gel polymer electrolyte

  • de Jong Derek,
  • Karst Julian,
  • Ludescher Dominik,
  • Floess Moritz,
  • Moell Sophia,
  • Dirnberger Klaus,
  • Hentschel Mario,
  • Ludwigs Sabine,
  • Braun Paul V.,
  • Giessen Harald

DOI
https://doi.org/10.1515/nanoph-2022-0654
Journal volume & issue
Vol. 12, no. 8
pp. 1397 – 1404

Abstract

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We present an electrically switchable, compact metasurface device based on the metallic polymer PEDOT:PSS in combination with a gel polymer electrolyte. Applying square-wave voltages, we can reversibly switch the PEDOT:PSS from dielectric to metallic. Using this concept, we demonstrate a compact, standalone, and CMOS compatible metadevice. It allows for electrically controlled ON and OFF switching of plasmonic resonances in the 2–3 µm wavelength range, as well as electrically controlled beam switching at angles up to 10°. Furthermore, switching frequencies of up to 10 Hz, with oxidation times as fast as 42 ms and reduction times of 57 ms, are demonstrated. Our work provides the basis towards solid state switchable metasurfaces, ultimately leading to submicrometer-pixel spatial light modulators and hence switchable holographic devices.

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