Microstructure evolution and enhanced mechanical properties in Al-Mn alloy reinforced by B-doped TiC particles

Abstract

In this work, novel TiC particles doped by trace amounts of B, referred to as TiCB, were introduced to an Al-Mn alloy with the Al-TCB master alloy. The effects of the TiCB particles on the solidification microstructure, extrusion behavior, and mechanical properties of the Al-Mn alloy were systematically studied. The results showed that TiCB particles could significantly refine α-Al grains by providing heterogeneous nucleation substrates and hindering the growth of α-grains. For example, when the amount of added TiCB particles was 0.5 wt%, average α-Al grain size could be refined to a minimum of 40.2 μm from 410.1 μm when no particles were added. After hot extrusion, TiCB particles and fractured α-Al(Fe, Mn)Si formed streamlines along the extrusion direction. More importantly, TiCB particles could inhibit the dynamic recrystallization process during hot extrusion and retain numerous geometrically necessary dislocations. Consequently, the mechanical properties of the Al-Mn alloy at room temperature (25 °C) and elevated temperature (350 °C) were significantly improved after adding TiCB particles. When the amount of added TiCB particles was 1.5 wt%, the ultimate tensile strengths at 25 °C and 350 °C were increased by 25.6% and 32.4%. This work sheds light on the grain refinement and strengthening of non-heat-treatable wrought Al-Mn alloys.

Keywords

• TiCB particles
• Al-Mn alloy
• Grain refinement
• Mechanical properties