Fast One-Step Synthesis of Anisotropic Silver Nanoparticles

Abstract

The shape control of metal nanoparticles, along with the size, is critical for most of their applications as they control their optical properties. Anisotropic metal nanoparticles show superior performance in a number of applications compared to spherical ones. Shape control is usually achieved by a two-step process, where the first involves the formation of spherical nanoparticles and the second is about the actual shape transformation. In this paper, we report on a fast and facile synthesis of silver nanoplates in a single step, involving laser ablation of a silver target in a liquid medium while this is exposed to light irradiation and hydrogen peroxide flow. We obtained anisotropic particles with a mixture of shapes, of 70–80 nm in size and 10–20 nm in thickness, which showed a plasmon sensitivity greater than 200 nm/RIU.

Keywords

• laser ablation
• silver nanoplates
• photochemistry
• plasmon sensitivity