Acta Crystallographica Section E (Oct 2011)

4-((E)-{2-[N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrazol-4-yl)carboximidoyl]benzylidene}amino)-1,5-dimethyl-2-phenyl-2,3-dihydro-1H-pyrazol-3-one

  • Richard Betz,
  • Thomas Gerber,
  • Eric Hosten,
  • Kim Potgieter

DOI
https://doi.org/10.1107/S1600536811039158
Journal volume & issue
Vol. 67, no. 10
pp. o2785 – o2786

Abstract

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The title compound, C30H28N6O2, is a symmetric diimine derived from ortho-dibenzaldehyde. Both C=N bonds are (E)-configured. The terminal N-bonded phenyl groups adopt staggered conformations relative to their respective parent heterocycles, the relevant least-squares planes intersect at angles of 32.35 (11) and 38.59 (10)°. In the crystal, C—H...O contacts connect the molecules into chains along the b axis and give rise to a C11(14)C11(14) and a R22(12) pattern on different levels of graph-set analysis. The shortest intercentroid distance between two centroids was found at 4.2074 (11) Å between the two five-membered heterocycles.