Ligand-controlled stereodivergent alkenylation of alkynes to access functionalized trans- and cis-1,3-dienes

Tianyu Long; Chen Zhu; Ling Li; Liang Shao; Shengqing Zhu; Magnus Rueping; Lingling Chu

doi:10.1038/s41467-022-35688-2

Nature Communications (Jan 2023)

Ligand-controlled stereodivergent alkenylation of alkynes to access functionalized trans- and cis-1,3-dienes

Tianyu Long,
Chen Zhu,
Ling Li,
Liang Shao,
Shengqing Zhu,
Magnus Rueping,
Lingling Chu

Affiliations

Tianyu Long: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, Donghua University, College of Chemistry and Chemical Engineering
Chen Zhu: King Abdullah University of Science and Technology (KAUST), KAUST Catalysis Center (KCC)
Ling Li: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, Donghua University, College of Chemistry and Chemical Engineering
Liang Shao: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, Donghua University, College of Chemistry and Chemical Engineering
Shengqing Zhu: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, Donghua University, College of Chemistry and Chemical Engineering
Magnus Rueping: King Abdullah University of Science and Technology (KAUST), KAUST Catalysis Center (KCC)
Lingling Chu: State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center for Advanced Low-Dimension Materials, Donghua University, College of Chemistry and Chemical Engineering

DOI: https://doi.org/10.1038/s41467-022-35688-2
Journal volume & issue: Vol. 14, no. 1
pp. 1 – 11

Abstract

Read online

The stereoselective synthesis of 1,3-dienes represents a challenge in organic synthesis. Here, the authors report a ligand-controlled stereodivergent access to both Z- and E-sulfonyl-1,3-dienes via photoredox and nickel catalysis.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

About the journal