Urea-Doped Calcium Phosphate Nanoparticles as Sustainable Nitrogen Nanofertilizers for Viticulture: Implications on Yield and Quality of Pinot Gris Grapevines
Federica Gaiotti,
Marco Lucchetta,
Giacomo Rodegher,
Daniel Lorenzoni,
Edoardo Longo,
Emanuele Boselli,
Stefano Cesco,
Nicola Belfiore,
Lorenzo Lovat,
José Manuel Delgado-López,
Francisco J. Carmona,
Antonietta Guagliardi,
Norberto Masciocchi,
Youry Pii
Affiliations
Federica Gaiotti
Council for Agricultural Research and Economics, Research Centre for Viticulture and Enology, Viale 28 Aprile 26, 31015 Conegliano, Italy
Marco Lucchetta
Council for Agricultural Research and Economics, Research Centre for Viticulture and Enology, Viale 28 Aprile 26, 31015 Conegliano, Italy
Giacomo Rodegher
Faculty of Science and Technology, Free University of Bozen-Bolzano, Piazza Università 5, 39100 Bolzano, Italy
Daniel Lorenzoni
Faculty of Science and Technology, Free University of Bozen-Bolzano, Piazza Università 5, 39100 Bolzano, Italy
Edoardo Longo
Faculty of Science and Technology, Free University of Bozen-Bolzano, Piazza Università 5, 39100 Bolzano, Italy
Emanuele Boselli
Faculty of Science and Technology, Free University of Bozen-Bolzano, Piazza Università 5, 39100 Bolzano, Italy
Stefano Cesco
Faculty of Science and Technology, Free University of Bozen-Bolzano, Piazza Università 5, 39100 Bolzano, Italy
Nicola Belfiore
Council for Agricultural Research and Economics, Research Centre for Viticulture and Enology, Viale 28 Aprile 26, 31015 Conegliano, Italy
Lorenzo Lovat
Council for Agricultural Research and Economics, Research Centre for Viticulture and Enology, Viale 28 Aprile 26, 31015 Conegliano, Italy
José Manuel Delgado-López
Departamento de Química Inorgánica, Universidad de Granada, av. Fuentenueva s/n, 18071 Granada, Spain
Francisco J. Carmona
Departamento de Química Inorgánica, Universidad de Granada, av. Fuentenueva s/n, 18071 Granada, Spain
Antonietta Guagliardi
Istituto di Cristallografia & To.Sca.Lab, Consiglio Nazionale delle Ricerche, via Valleggio 11, 22100 Como, Italy
Norberto Masciocchi
Dipartimento di Scienza e Alta Tecnologia & To.Sca.Lab, Università dell’Insubria, via Valleggio 11, 22100 Como, Italy
Youry Pii
Faculty of Science and Technology, Free University of Bozen-Bolzano, Piazza Università 5, 39100 Bolzano, Italy
In recent years, the application of nanotechnology for the development of new “smart fertilizers” is regarded as one of the most promising solutions for boosting a more sustainable and modern grapevine cultivation. Despite showing interesting potential benefits over conventional fertilization practices, the use of nanofertilizers in viticulture is still underexplored. In this work, we investigated the effectiveness of non-toxic calcium phosphate nanoparticles (Ca3(PO4)2∙nH2O) doped with urea (U-ACP) as a nitrogen source for grapevine fertilization. Plant tests were performed for two years (2019–2020) on potted adult Pinot gris cv. vines grown under semi-controlled conditions. Four fertilization treatments were compared: N1: commercial granular fertilization (45 kg N ha−1); N2: U-ACP applied in fertigation (36 kg N ha−1); N3: foliar application of U-ACP (36 kg N ha−1); C: control, receiving no N fertilization. Plant nitrogen status (SPAD), yield parameters as well as those of berry quality were analyzed. Results here presented clearly show the capability of vine plants to recognize and use the nitrogen supplied with U-ACP nanoparticles either when applied foliarly or to the soil. Moreover, all of the quali–quantitative parameters measured in vine plants fed with nanoparticles were perfectly comparable to those of plants grown in conventional condition, despite the restrained dosage of nitrogen applied with the nanoparticles. Therefore, these results provide both clear evidence of the efficacy of U-ACP nanoparticles as a nitrogen source and the basis for the development of alternative nitrogen fertilization strategies, optimizing the dosage/benefit ratio and being particularly interesting in a context of a more sustainable and modern viticulture.