Inhibition of mild steel corrosion using Jatropha Curcas leaf extract

Journal of Electrochemical Science and Engineering. 2014;4(2):67-74 DOI 10.5599/jese.2014.0046

 

Journal Homepage

Journal Title: Journal of Electrochemical Science and Engineering

ISSN: 1847-9286 (Online)

Publisher: International Association of Physical Chemists (IAPC)

LCC Subject Category: Science: Chemistry: Physical and theoretical chemistry | Technology: Chemical technology: Chemical engineering

Country of publisher: Croatia

Language of fulltext: English

Full-text formats available: PDF

 

AUTHORS

OLORUNFEMI MICHAEL AJAYI (Department of Mechanical Engineering, University of Ilorin, Ilorin, Nigeria)
JAMIU KOLAWOLE ODUSOTE (Department of Materials and Metallurgical Engineering, University of Ilorin, Ilorin, Nigeria)
RAHEEM ABOLORE YAHYA (Department of Materials and Metallurgical Engineering, University of Ilorin, Ilorin, Nigeria)

EDITORIAL INFORMATION

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Time From Submission to Publication: 6 weeks

 

Abstract | Full Text

Jatropha Curcas leaf was investigated as a green inhibitor on the degradation of mild steel in 4 M HCl and 4 M H2SO4 aqueous solutions using gasometric technique. Mild steel coupons of dimension 2 × 1.5 cm were immersed in test solutions of uninhibited acid and also those with extract concentrations of 4 ml, 6 ml, 8 ml and 10 ml at 30 oC, for up to 30 minutes. The results showed that as the concentration of the extract increases, there was reduction in the corrosion rate. As the extract concentration increased from 4 ml to 10 ml at 30 minutes exposure, the volume of hydrogen gas evolved decreased from 19.1 cm3 to 11.2 cm3 in H2SO4 medium, while it reduced to 5 cm3 from 9 cm3 in HCl medium. Also, the metal surface-phytoconstituent interaction mechanism showed that 6 minutes is the best exposure time for the adsorption of the extract in both acidic media. The Jatropha Curcas leaf extract was adsorbed on the mild steel surface to inhibit corrosion, while the experimental data obtained at 30 minutes exposure in both acidic media were well fitted with the Langmuir adsorption isotherm. Hence, Jatropha Curcas leaf extract is a good and safe inhibitor in both acidic solutions.