Synthesis and Characterization of Some New Metals Complexes of [N-(4-Nitrobenzoyl Amino)-Thioxomethyl] Phenylalanine

Baghdad Science Journal. 2016;13(1) DOI 10.21123/bsj.13.1.113-121

 

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Journal Title: Baghdad Science Journal

ISSN: 2078-8665 (Print); 2411-7986 (Online)

Publisher: College of Science for Women, University of Baghdad

LCC Subject Category: Science

Country of publisher: Iraq

Language of fulltext: Arabic, English

Full-text formats available: PDF

 

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Baghdad Science Journal

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Blind peer review

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Time From Submission to Publication: 24 weeks

 

Abstract | Full Text

A new ligand [N-(4-nitrobenzoylamino)-thioxomethyl] phenylalanine is synthesized by reaction of 4-nitrobenzoyl isothiocyanate with phenylalanine (1:1). It is characterized by micro elemental analysis (C.H.N.S.), FT-IR, (UV-Vis) and 1H and 13CNMR spectra. Some metals ions complexes of this ligand were prepared and characterized by FT-IR, UV-Visible spectra, conductivity measurements, magnetic susceptibility and atomic absorption. From results obtained, the following formula [M(NBA)2] where M2+ = Mn, Co, Ni, Cu, Zn, Pd, Cd and Hg, the proposed molecular structure for these complexes as tetrahedral geometry, except copper and palladium complexes are have square planer geometry.