Acta Crystallographica Section E (Jul 2011)

Diazido{(S)-1-phenyl-N,N-bis[(2-pyridyl)methyl]ethanamine}copper(II)

  • Sankara Rao Rowthu,
  • Jong Won Shin,
  • Seung-Hui Kim,
  • Jong Jin Kim,
  • Kil Sik Min

DOI
https://doi.org/10.1107/S1600536811021234
Journal volume & issue
Vol. 67, no. 7
pp. m873 – m874

Abstract

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In the title compound, [Cu(N3)2(C20H21N3)], the CuII ion is coordinated by the three N atoms of the (S)-1-phenyl-N,N-bis[(2-pyridyl)methyl]ethanamine ligand and two N atoms from two azide anions, resulting in a distorted square-pyramidal environment. A weak intermolecular C—H...N hydrogen-bonding interaction between one pyridine group of the ligand and an azide N atom of an adjacent complex unit gives a one-dimensional chain structure parallel to the c axis.