In Situ Formation of Surface-Induced Oxygen Vacancies in Co₉S₈/CoO/NC as a Bifunctional Electrocatalyst for Improved Oxygen and Hydrogen Evolution Reactions

Abstract

Creating oxygen vacancies and introducing heterostructures are two widely used strategies in Co-based oxides for their efficient electrocatalytic performance, yet both strategies have rarely been used together to design a bifunctional electrocatalyst for an efficient overall water splitting. Herein, we propose a facile strategy to synthesize oxygen-defect-rich Co9S8/CoO hetero-nanoparticles with a nitrogen-doped carbon shell (ODR-Co9S8/CoO/NC) through the in situ conversion of heterojunction along with surface-induced oxygen vacancies, simply via annealing the precursor Co3S4/Co(OH)2/ZIF-67. The as-prepared ODR-Co9S8/CoO/NC shows excellent bifunctional catalytic activities, featuring a low overpotential of 217 mV at 10 mA cm−2 in the oxygen evolution reaction (OER) and 160 mV at 10 mA cm−2 in the hydrogen evolution reaction (HER). This performance excellency is attributed to unique heterostructure and oxygen defects in Co9S8/CoO nanoparticles, the current work is expected to offer new insights to the design of cost-effective, noble-metal-free electrocatalysts.

Keywords

• oxygen vacancies
• heterojunction
• oxygen evolution reaction
• hydrogen evolution reaction