Acta Crystallographica Section E (Apr 2014)

Triphenyltellurium chloride

  • Ambika Chopra,
  • Shalini Jain,
  • Sanjay K. Srivastava,
  • Sushil K. Gupta,
  • Ray J. Butcher

DOI
https://doi.org/10.1107/S160053681400498X
Journal volume & issue
Vol. 70, no. 4
pp. o421 – o422

Abstract

Read online

The asymmetric unit of the title compound, C18H15ClTe, contains two molecules which are in inverted orientations. The compound displays a tetrahedral geometry around the Te atom in spite of there being five electron domains. This is attributed to the fact that the lone pair is not sterically active. The dihedral angles between the three phenyl rings are 76.51 (16)/73.75 (16)/71.06 (17) and 78.60 (17)/77.67 (16)/79.11 (16)° in the two molecules. The crystal packing features eight C—H...π interactions.