Humidification of polymer electrolyte membranes in fuel cells is essential for high proton conductivity and lifetime, therefore often membrane humidifier modules are used. We report about the degradation of polyimide humidifier membranes under the influence of airborne ozone traces: during operation we tracked the membranes humidifier performance in 5 modules for up to 1000 h with trace levels of ozone (100 ppb) and conducted characterization tests at 200 h intervals. Operating the humidifier with ozone resulted in a linear decrease in the membrane's ability to transfer moisture over time. Moreover, the glass transition temperature of the membrane material decreases linearly with longer exposure to ozone, while the mechanical strength in terms of breaking force and elongation at break decreases too. Infrared spectra of the tested fibers showed no changes. The reduced water vapor flux would limit fuel cell performance, while the reduced mechanical properties of the membrane can lead to rupture.
