A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins

Dimitra Daphnomili; Maria Grammatikopoulou; Catherine Raptopoulou; George Charalambidis; Theodore Lazarides; Athanasios G. Coutsolelos

doi:10.1155/2010/307696

Bioinorganic Chemistry and Applications (Jan 2010)

A Synthetic Approach of New Trans-Substituted Hydroxylporphyrins

Dimitra Daphnomili,
Maria Grammatikopoulou,
Catherine Raptopoulou,
George Charalambidis,
Theodore Lazarides,
Athanasios G. Coutsolelos

Affiliations

Dimitra Daphnomili: Laboratory of Bioinorganic Coordination Chemistry, Department of Chemistry, School of Sciences, University of Crete, P.O. Box 2208, Heraklion 71003, Crete, Greece
Maria Grammatikopoulou: Laboratory of Bioinorganic Coordination Chemistry, Department of Chemistry, School of Sciences, University of Crete, P.O. Box 2208, Heraklion 71003, Crete, Greece
Catherine Raptopoulou: Institute of Materials Science, NCSR “Demokritos”, Aghia Paraskevi Attikis, 15310, Greece
George Charalambidis: Laboratory of Bioinorganic Coordination Chemistry, Department of Chemistry, School of Sciences, University of Crete, P.O. Box 2208, Heraklion 71003, Crete, Greece
Theodore Lazarides: Laboratory of Bioinorganic Coordination Chemistry, Department of Chemistry, School of Sciences, University of Crete, P.O. Box 2208, Heraklion 71003, Crete, Greece
Athanasios G. Coutsolelos: Laboratory of Bioinorganic Coordination Chemistry, Department of Chemistry, School of Sciences, University of Crete, P.O. Box 2208, Heraklion 71003, Crete, Greece

DOI: https://doi.org/10.1155/2010/307696
Journal volume & issue: Vol. 2010

Abstract

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The synthesis of new trans A2B2-substituted porphyrins bearing oxygenic substituent (methoxy, acetoxy, hydroxy) at the periphery of the ring are described. All of the synthesized products were characterized by H-N.M.R., C-N.M.R., and H.R.M.S. Electrochemical studies revealed two one-electron oxidations and two reductions. In addition, the X-ray structure of one methoxy-derivative was determined.

Published in Bioinorganic Chemistry and Applications

ISSN: 1565-3633 (Print); 1687-479X (Online)
Publisher: Hindawi Limited
Country of publisher: United Kingdom
LCC subjects: Technology: Chemical technology: Biotechnology; Science: Chemistry: Inorganic chemistry
Website: https://onlinelibrary.wiley.com/journal/4036

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