Polymers (Oct 2022)
Microstructural and Thermo-Mechanical Characterization of Furfurylated Douglas Fir
Abstract
Fast-growing wood has become a major source of materials for the wood industry in recent years, but defects have limited its use. Therefore, modification is urgently needed for the more efficient application of wood products. In this study, a 30 to 50% solution of furfuryl alcohol (FA) was impregnated into Douglas fir sapwood. The microstructure and thermal properties of the specimens before and after furfurylation were evaluated by different techniques. The weight percentage gain (WPG) of modified wood increased up to 22.97%, with the polymerized FA distributed in cell lumens and cell walls, as well as chemically bound to wood components. The polyfurfuryl alcohol (PFA) was mainly located in the tracheids, ray parenchyma cells, and resin canals. In addition, the furfurylated cell walls were greatly thickened. Raman spectra showed that modified wood had significant background fluorescence that covered other peaks. Differential Scanning Calorimetry analysis revealed that the cross-linking reaction between FA and wood changed the shape of curves, with no endothermic or exothermic peaks within the programmed temperature. Moreover, Thermogravimetry and Dynamic Mechanical Analysis results both confirmed that the furfurylation increased the thermal stability of Douglas fir. The percentage of the final mass loss of untreated specimen was 80.11%, while the highest one of furfurylated specimen was 78.15%, and it gradually decreased with increasing FA concentration. The storage modulus (E′) and loss modulus (E″) of the furfurylated wood were both lower, and the damping factor (tan δ) was higher than the untreated one. When the temperature reaches about 75 °C, the untreated specimen began to soften and deform. At 90 °C, it fractured completely while the furfurylatedone remained stable. This study demonstrated that furfurylation can improve wood properties and elongate its service life.
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