Hydrogen Evolution Reaction Activities of Room-Temperature Self-Grown Glycerol-Assisted Nickel Chloride Nanostructures

Abstract

Three-dimensional nanomaterials of desired structural/morphological properties and highly porous with a high specific surface area are important in a variety of applications. In this work, glycerol-mediated self-growth of 3-D dandelion flower-like nickel chloride (NiCl2) from nickel-foam (NiF) is obtained for the first time using a room-temperature (27 °C) processed wet chemical method for electrocatalysis application. Glycerol-mediated self-grown NiCl2 flowers demonstrate an excellent electrocatalytic performance towards the hydrogen evolution reaction (HER), which is much superior to the NiF (303 mV) and NiCl2 electrode prepared without glycerol (208 mV) in the same electrolyte solution. With a Tafel slope of 41 mV dec−1, the NiCl2 flower electrode confirms improved reaction kinetics as compared to the other two electrodes, i.e., NiF (106 mVdec−1) and NiCl2 obtained without glycerol (56 mV dec−1). The stability of the glycerol-based NiCl2 electrode has further been carried out for 2000 cycles with the overpotential diminution of just 8 mV, approving an electrocatalyst potential of glycerol-based NiCl2 electrode towards HER kinetics. This simple and easy growth process involves nucleation, aggregation, and crystal growth steps for producing NiCl2 nanostructures for electrocatalytic water splitting application through the HER process.

Keywords

• self-grown nanostructures
• NiCl₂
• structural elucidation and morphology evolution
• electrocatalysis