Discontinuous Dissolution Reaction in a Fe-13.5 at. % Zn Alloy

Abstract

The dissolution process of a lamellar structure with α and Γ phases formed during a discontinuous precipitation reaction is investigated here with a Fe-13.5 at. % Zn alloy by means of optical microscopy and scanning and transmission electron microscopy. The α phase is a solute-depleted solid solution and the Γ phase is the intermetallic compound Fe3Zn10. The examination reveals that the dissolution occurs in a discontinuous mode by a receding of the former reaction front of the discontinuous precipitation towards the position of the original grain boundary. A new solid solution in the post-dissolution area is especially inhomogeneous and reflects the former locations of the Γ lamellae (“ghost images”) and the receding reaction front (“ghost lines”). A simulation procedure is applied to determine the Zn concentration profiles left in the post-dissolution region. Their shapes are mostly affected by the Zn content at the positions where the Γ lamellae have just been dissolved, which was also confirmed by the quantitative microchemical analysis.

Keywords

• discontinuous dissolution
• diffusion at moving boundaries
• solute concentration profiles
• TEM/EDX microanalysis
• Fe-Zn system