Superior Electrocatalytic Activity of MoS<sub>2</sub>-Graphene as Superlattice
Alejandra Rendón-Patiño,
Antonio Domenech-Carbó,
Ana Primo,
Hermenegildo García
Affiliations
Alejandra Rendón-Patiño
Instituto de Tecnología Química (CSIC-UPV) and Department of Chemistry, Consejo Superior de Investigaciones Científicas-Universitat Politècnica de Valencia, Avenida de los Naranjos s/n, 46022 Valencia, Spain
Antonio Domenech-Carbó
Departamento de Química Analítica, Universitat de Valencia, Av. Del Dr. Moliner s/n, 46100 Burjassot, Spain
Ana Primo
Instituto de Tecnología Química (CSIC-UPV) and Department of Chemistry, Consejo Superior de Investigaciones Científicas-Universitat Politècnica de Valencia, Avenida de los Naranjos s/n, 46022 Valencia, Spain
Hermenegildo García
Instituto de Tecnología Química (CSIC-UPV) and Department of Chemistry, Consejo Superior de Investigaciones Científicas-Universitat Politècnica de Valencia, Avenida de los Naranjos s/n, 46022 Valencia, Spain
Evidence by selected area diffraction patterns shows the successful preparation of large area (cm × cm) MoS2/graphene heterojunctions in coincidence of the MoS2 and graphene hexagons (superlattice). The electrodes of MoS2/graphene in superlattice configuration show improved catalytic activity for H2 and O2 evolution with smaller overpotential of +0.34 V for the overall water splitting when compared with analogous MoS2/graphene heterojunction with random stacking.