Ni(II) and Cu(II) Ion Coordination by the Novel (2<i>E</i>,2′<i>E</i>)-<i>N</i>,<i>N</i>′-(2-Hydroxypropane-1,3-diyl)<i>bis</i>[(2-hydroxyimino)propanamide] Ligand in the Solid State and in Aqueous Medium

Abstract

In the process of a systematic study of the bis-chelate oxime-amide ligands with different polymethylene spacers and their transition metal complexes, two new Ni(II) and Cu(II) complexes of the mhiea2poh ligand have been isolated, and their molecular and crystal structures determined by single crystal X-ray diffraction. Potentiometric titrations were performed on a range of aqueous solutions in both systems, which allowed the identification of various complex species and afforded their stability constants. ESR spectra of samples with optimised concentrations of complexes in Cu(II)–L–H system were recorded. A distinguishing feature of both systems is the dimerization of anionic pseudo-macrocyclic complexes. The latter is caused either by centrosymmetric hydrogen bonding of the hydroxy group on the propane spacer to the oximato oxygen of the opposing unit or by back-to-back π-stacking of planar complex units. ESR measurements indicated likely coupling of Cu-Cu paramagnetic centres in the dimers.

Keywords

• Ni(II) and Cu(II) complexes of novel <i>bis</i>-chelate oxime-amide ligand
• single crystal X-ray diffraction
• molecular and crystal structures
• potentiometric titrations
• stability constants
• ESR spectra