Stretchable, self‐healable, and breathable biomimetic iontronics with superior humidity‐sensing performance for wireless respiration monitoring
Qiongling Ding,
Hao Wang,
Zijing Zhou,
Zixuan Wu,
Kai Tao,
Xuchun Gui,
Chuan Liu,
Wenxiong Shi,
Jin Wu
Affiliations
Qiongling Ding
State Key Laboratory of Optoelectronic Materials and Technologies, the Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technology Sun Yat‐sen University Guangzhou China
Hao Wang
State Key Laboratory of Optoelectronic Materials and Technologies, the Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technology Sun Yat‐sen University Guangzhou China
Zijing Zhou
State Key Laboratory of Optoelectronic Materials and Technologies, the Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technology Sun Yat‐sen University Guangzhou China
Zixuan Wu
State Key Laboratory of Optoelectronic Materials and Technologies, the Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technology Sun Yat‐sen University Guangzhou China
Kai Tao
Ministry of Education Key Laboratory of Micro and Nano Systems for Aerospace Northwestern Polytechnical University Xi'an China
Xuchun Gui
State Key Laboratory of Optoelectronic Materials and Technologies, the Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technology Sun Yat‐sen University Guangzhou China
Chuan Liu
State Key Laboratory of Optoelectronic Materials and Technologies, the Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technology Sun Yat‐sen University Guangzhou China
Wenxiong Shi
Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science and Engineering Tianjin University of Technology Tianjin China
Jin Wu
State Key Laboratory of Optoelectronic Materials and Technologies, the Guangdong Province Key Laboratory of Display Material and Technology, School of Electronics and Information Technology Sun Yat‐sen University Guangzhou China
Abstract Stretchable, self‐healing, and breathable skin‐biomimetic‐sensing iontronics play an important role in human physiological signal monitoring and human–computer interaction. However, previous studies have focused on the mimicking of skin tactile sensing (pressure, strain, and temperature), and the development of more functionalities is necessary. To this end, a superior humidity‐sensitive ionic skin is developed based on a self‐healing, stretchable, breathable, and biocompatible polyvinyl alcohol–cellulose nanofibers organohydrogel film, showing a pronounced thickness‐dependent humidity‐sensing performance. The as‐prepared 62.47‐μm‐thick organohydrogel film exhibits a high response (25,000%) to 98% RH, excellent repeatability, and long‐term stability (120 days). Moreover, this ionic skin has excellent resistance to large mechanical deformation and damage, and the worn‐out material can still retain its humidity‐sensing capabilities after self‐repair. Humidity‐sensing mechanism studies show that the induced response is mainly related to the increase of proton mobility and interfacial charge transport efficiency after water adsorption. The superior humidity responsiveness is attributed to the reduced thickness and the increased specific surface area of the organohydrogel film, allowing real‐time recording of physiological signals. Notably, by combining with a self‐designed printed circuit board, a continuous and wireless respiration monitoring system is developed, presenting its great potential in wearable and biomedical electronics.
