Eksplorium: Buletin Pusat Pengembangan Bahan Galian Nuklir (Nov 2017)

Model Matematik Reduksi Thorium dalam Proses Elektrokoagulasi

  • Prayitno ,
  • Vemi Ridantami

DOI
https://doi.org/10.17146/eksplorium.2017.38.2.3566
Journal volume & issue
Vol. 38, no. 2
pp. 121 – 132

Abstract

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Thorium reduction by electrocoagulation has been conducted on radioactive waste with thorium contaminant grade of 5x10-4Kg/l through a batch system using aluminium electrodes. This study aims to determine a mathematical model of thorium reduction through speed reaction, constante reaction rate and reaction order which are affected by electrocoagulation process parameters like voltage, time, electrode distance, and pH. The research results the optimum voltage condition at 12.5 V at 1 cm electrode spacing, pH 7, and 30 minutes of processing time with 99.6 % efficiency. Prediction on thorium decline rate constante is obtained through mathematic integral method calculation. The research results thorium decline rate is following second order constante with its value at 5x10-3KgL-1min-1.

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