Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid

Zhe An; Zilong Zhang; Zeyu Huang; Hongbo Han; Binbin Song; Jian Zhang; Qi Ping; Yanru Zhu; Hongyan Song; Bin Wang; Lirong Zheng; Jing He

doi:10.1038/s41467-022-33038-w

Nature Communications (Sep 2022)

Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid

Zhe An,
Zilong Zhang,
Zeyu Huang,
Hongbo Han,
Binbin Song,
Jian Zhang,
Qi Ping,
Yanru Zhu,
Hongyan Song,
Bin Wang,
Lirong Zheng,
Jing He

Affiliations

Zhe An: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology
Zilong Zhang: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology
Zeyu Huang: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology
Hongbo Han: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology
Binbin Song: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology
Jian Zhang: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology
Qi Ping: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology
Yanru Zhu: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology
Hongyan Song: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology
Bin Wang: Beijing Research Institute of Chemical Industry, Sinopec Group
Lirong Zheng: Technology Institute of High Energy Physics, Chinese Academy of Sciences
Jing He: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology

DOI: https://doi.org/10.1038/s41467-022-33038-w
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 13

Abstract

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The selective oxidation of glycerol to glyceric acid is an important value-added cascade catalytic process. Here the authors report a cascade synergistic catalysis strategy by atomic and low-coordinated cluster Pt on well-defined Cu-CuZrOx to simultaneously achieve high activity and selectivity.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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