Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent

Yang Xiaoyuan; Liu Jing; Kan Qiubin; Guan Jingqi

doi:10.2478/pjct-2014-0043

Polish Journal of Chemical Technology (Sep 2014)

Anchoring Tri(8-Quinolinolato)Iron Onto Sba-15 for Partial Oxidation of Benzyl Alcohol Using Water as the Solvent

Yang Xiaoyuan,
Liu Jing,
Kan Qiubin,
Guan Jingqi

Affiliations

Yang Xiaoyuan: Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR China
Liu Jing: Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR China
Kan Qiubin: Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR China
Guan Jingqi: Jilin University, Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Changchun, 130023, PR China

DOI: https://doi.org/10.2478/pjct-2014-0043
Journal volume & issue: Vol. 16, no. 3
pp. 12 – 17

Abstract

Read online

Tri(8-quinolinolato)iron complex immobilized onto SBA-15 catalyst has been synthesized through a stepwise procedure. The characterization results indicated that the BET surface area, total pore volume and average pore width decrease after stepwise modification of SBA-15, while the structure keeps intact. Catalytic tests showed that FeQ3-SBA-15 catalyzes the oxidation reaction well with 34.8% conversion of benzyl alcohol and 74.7% selectivity to benzaldehyde when water is used as the solvent after 1 h reaction. In addition, homogeneous catalyst tri(8-quinolinolato)iron exhibits very bad catalytic behavior using water as the solvent.

Published in Polish Journal of Chemical Technology

ISSN: 1899-4741 (Online)
Publisher: Sciendo
Country of publisher: Poland
LCC subjects: Science: Chemistry
Website: https://sciendo.com/journal/PJCT

About the journal

Abstract

Keywords