The Surface Free Energy of Resin-Based Composite in Context of Wetting Ability of Dental Adhesives

Abstract

The surface roughness, surface free energy (SFE) of composites, and composite wettability by dental adhesives are determining factors in achieving a strong and durable adhesion (e.g., composite repair, luting adhesively bonded indirect restorations). In this study, the SFE of one nanohydrid and two bulk-fill composites was investigated in relation to the wetting ability of five different dental adhesives. The profilometry and scanning electron microscopy (SEM) measurement justified that the sandblasting produced a significantly rough surface in which the different filler amounts, filler distribution, and resin-filler ratio participated. The SFE of the tested composite was between 45.65 and 49.07 mJ/m2 regardless of surface treatment. Despite the similarity in SFE, the adhesives wet the surface of the composites in different ways that were between 16.01° and 35.10°. The contact angle of solvent-free dental adhesive was lower due to sandblasting supporting the micromechanical retention. Based on our results, it was found that sandblasting, the most frequently recommended surface treatment, does not change the surface energy but causes a change in the contact angle, which can be explained by the different surface tension of the dental adhesives. It was concluded that the dental adhesive parameters have a more important role in wettability.

Keywords

• resin-based composite
• contact angle
• dental adhesive
• surface free energy
• surface roughness