Adsorption Thermodynamics and Kinetics of Resin for Metal Impurities in Bis(2-hydroxyethyl) Terephthalate
Noor Fatima,
Qi Zhang,
Ruru Chen,
Dongxia Yan,
Qing Zhou,
Xingmei Lu,
Jiayu Xin
Affiliations
Noor Fatima
School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Qi Zhang
School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Ruru Chen
Beijing Key Laboratory of Ionic Liquids Clean Process, CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
Dongxia Yan
Beijing Key Laboratory of Ionic Liquids Clean Process, CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
Qing Zhou
Beijing Key Laboratory of Ionic Liquids Clean Process, CAS Key Laboratory of Green Process and Engineering, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
Xingmei Lu
School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Jiayu Xin
School of Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
Adsorption of heavy metals from degraded of Polyethylene terephthalate (PET) products by strong cation exchange resin AmberliteIR-120 under optimized conditions toward the selectivity removal of metals are in the following order: Al3+ > Zn2+ > Mg2+ > Fe2+ > Ni2+. Therefore, kinetic and adsorption isotherm models were applied for fitting experimental data. Comparatively, adsorption isotherm study revealed that Langmuir isotherm model better fits adsorption on surface of resin over than the Freundlich model. In summary, AmberliteIR-120 strong acid cation exchange resin can be used as an efficient adsorbent for heavy metals removal from depolymerized products bis(2-hydroxyethyl) terephthalate.