Controlling pairing of π-conjugated electrons in 2D covalent organic radical frameworks via in-plane strain

Abstract

Controlling the electronic states of molecules is a fundamental challenge for future sub-nanoscale device technologies but the external dynamical control of these states still awaits experimental realization. Here, via quantum chemical calculations, the authors demonstrate that in-plane uniaxial strain of 2D covalently linked arrays of radical units induces controlled pairing of π-conjugated electrons in a reversible way.