Composite Modified Graphite Felt Anode for Iron–Chromium Redox Flow Battery

Abstract

The iron–chromium redox flow battery (ICRFB) has a wide range of applications in the field of new energy storage due to its low cost and environmental protection. Graphite felt (GF) is often used as the electrode. However, the hydrophilicity and electrochemical activity of GF are poor, and its reaction reversibility to Cr3+/Cr2+ is worse than Fe2+/Fe3+, which leads to the hydrogen evolution side reaction of the negative electrode and affects the efficiency of the battery. In this study, the optimal composite modified GF (Bi-Bio-GF-O) electrode was prepared by using the optimal pomelo peel powder modified GF (Bio-GF-O) as the matrix and further introducing Bi3+. The electrochemical performance and material characterization of the modified electrode were analyzed. In addition, using Bio-GF-O as the positive electrode and Bi-Bio-GF-O as the negative electrode, the high efficiency of ICRFB is realized, and the capacity attenuation is minimal. When the current density is 100 mA·cm−2, after 100 cycles, the coulomb efficiency (CE), voltage efficiency (VE), and energy efficiency (EE) were 97.83%, 85.21%, and 83.36%, respectively. In this paper, the use of pomelo peel powder and Bi3+ composite modified GF not only promotes the electrochemical performance and reaction reversibility of the negative electrode but also improves the performance of ICRFB. Moreover, the cost of the method is controllable, and the process is simple.

Keywords

• energy storage
• iron–chromium redox flow battery
• graphite felt
• Bi³⁺
• battery efficiency