Acta Crystallographica Section E (Jul 2008)

Tetracarbonylbis(η5-cyclopentadienyl)bis(diphenylphosphine)dimolybdenum(Mo—Mo) hexane solvate

  • David R. Tyler,
  • Lev N. Zakharov,
  • Stephanie A. Bossé,
  • Ginger V. Shultz

DOI
https://doi.org/10.1107/S1600536808017996
Journal volume & issue
Vol. 64, no. 7
pp. m940 – m940

Abstract

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The title compound, [Mo2(C5H5)2(C12H11P)2(CO)4]·C6H14, is a centrosymmetric Mo complex in which two Mo atoms are connected by an Mo—Mo bond [3.2072 (12) Å]. Each Mo atom is coordinated by an η5-cyclopentadienyl ligand, two carbonyl ligands and a diphenylphosphine ligand in a piano-stool fashion.