Local Corrosion Behaviors in the Coarse-Grained Heat-Affected Zone in a Newly Developed Zr–Ti–Al–RE Deoxidized High-Strength Low-Alloy Steel

Abstract

Oxide metallurgy technology can improve the microstructure of a coarse-grained heat-affected zone (CGHAZ) but introduces extra inclusions. Local corrosion behavior of the CGHAZ of a Zr–Ti–Al–RE deoxidized steel was investigated in this work using theoretical calculations and experimental verification. The modified inclusions have a (Zr–Mg–Al–Ca–RE)Ox core claded by a CaS and TiN shell. CaS dissolves first, followed by the oxide core, leaving TiN parts. This confirms that the addition of rare earth can reduce lattice distortion and prevent a galvanic couple between the inclusions and the matrix, while the chemical dissolution of CaS causes localized acidification, resulting in the pitting corrosion initiation.

Keywords

• inclusion
• pitting corrosion
• HSLA steel
• CGHAZ
• first-principles
• rare earth elements