Advance in the Synthesis of Sulfoxides and Sulfinamides from <i>β</i>-Sulfinyl Esters

Abstract

Sulfoxides and sulfinamides play important roles in the pharmaceutical industry, organic synthesis and fine chemicals. This review will demonstrate that, under catalysis by transition metals, β-sulfinyl esters, as nucleophilic reagents, react with a variety of electrophilic reagents to produce sulfoxides and sulfinamides. The important prospect of the asymmetric catalytic synthesis of chiral sulfur-containing molecules in this field is described.

Keywords

• <i>β</i>-sulfinyl esters
• sulfenate anions
• sulfoxides
• sulfinamides
• review