Acta Crystallographica Section E (Dec 2009)

Methanol{2-methoxy-6-[(2-oxidopropyl)iminomethyl]phenolato}dioxidomolybdenum(VI)

  • Helen Stoeckli-Evans,
  • Samira Saeednia,
  • Iran Sheikhshoaie

DOI
https://doi.org/10.1107/S1600536809047485
Journal volume & issue
Vol. 65, no. 12
pp. m1591 – m1591

Abstract

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In the structure of the title compound, [Mo(C11H13NO3)O2(CH3OH)], the MoVI ion is octahedrally coordinated by two oxide O atoms, the N atom and two deprotonated OH groups of the tridentate Schiff base ligand 2-methoxy-6-[(2-oxidopropyl)iminomethyl]phenolate and by a methanol O atom. In the crystal structure, two complexes are linked via O—H...O hydrogen bonds, yielding a centrosymmetric arrangement involving the methanol hydroxy group and one of the ligand O atoms coordinated to the MoVI ion.