Facile Separation of Cu²⁺ from Water by Novel Sandwich NaY Zeolite Adsorptive Membrane

Abstract

Polyethersulfone-sulfonated polyethersulfone (PES-SPES)/NaY zeolite/nylon sandwich structure membranes were prepared and used to adsorb Cu2+ from water. The adsorption kinetics, adsorption isotherm, dynamic adsorption experiment, and reusability were discussed. The experimental data showed that the Langmuir isotherm model, Dubinin–Radushkevich (D-R) isotherm model, and the pseudo-first-order kinetic model can well represent the adsorption of Cu2+ on the membrane, indicating an ion exchange mechanism, with the maximum adsorption capacity of 111.25 mg·g−1. Repeatability experiments show that the sandwich film still has good adsorption performance after five times of adsorption and desorption. The as-prepared membrane showed considerable separation performance in removing Cu2+ from aspirin solution, providing a feasible method to remove heavy metals from drugs.

Keywords

• adsorptive membrane
• sandwich structure
• NaY zeolite
• Cu²⁺