Nature Communications (Jun 2016)

Ambiphilic boron in 1,4,2,5-diazadiborinine

  • Baolin Wang,
  • Yongxin Li,
  • Rakesh Ganguly,
  • Hajime Hirao,
  • Rei Kinjo

DOI
https://doi.org/10.1038/ncomms11871
Journal volume & issue
Vol. 7, no. 1
pp. 1 – 10

Abstract

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Boranes are archetypal Lewis acids owing to an empty p-orbital on the boron, although Lewis basic tricoordinate boranes have been developed too. Here, the authors report an annulated 1,4,2,5-diazadiborinine derivative with boron atoms that exhibit both Lewis acidic and basic properties.