Bis[2-(1,3-benzothiazol-2-yl)phenyl-κ2C1,N][1,3-bis(4-bromophenyl)propane-1,3-dionato-κ2O,O′]iridium(III)

Abstract

The title complex, [Ir(C15H9Br2O2)(C13H8NS)2], lies about a crystallographic twofold rotation axis passing through the IrIII atom and the central C atom of the bis(bromophenyl)propane-1,3-dionate ligand. The IrIII atom adopts a distorted octahedral geometry coordinated by two N atoms in the axial positions, and two C and two O atoms in the equatorial plane. The dihedral angle between the two thiazole ring systems in the complex is 77.45 (10)°.