Nature Communications (Apr 2020)

Stereoselective gridization and polygridization with centrosymmetric molecular packing

  • Dongqing Lin,
  • Ying Wei,
  • Aizhong Peng,
  • He Zhang,
  • Chunxiao Zhong,
  • Dan Lu,
  • Hao Zhang,
  • Xiangping Zheng,
  • Lei Yang,
  • Quanyou Feng,
  • Linghai Xie,
  • Wei Huang

DOI
https://doi.org/10.1038/s41467-020-15401-x
Journal volume & issue
Vol. 11, no. 1
pp. 1 – 11

Abstract

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Gridarenes with well-defined edges and vertices represent versatile nanoscale building blocks for installating frameworks but suffer from lack of stereoselective control during their synthesis. Here, the authors report a diastereoselective gridization of superelectrophilic diazafluorene-containing substrates with crescent shapes into Drawing Hands grids (DHGs).