Green synthesis of stretchable ethyl cellulose film plasticized with transesterified sunflower oil

Abstract

Sustainability and environmental consciousness drive research toward biomaterials and green synthesis. Traditional plasticizers derived from non-renewable sources have raised concerns due to their adverse impact on the environment and human health. As a result, there is a growing interest in replacing these traditional plasticizers with inexpensive naturally derived alternatives. One such promising compound that has gained considerable attention is vegetable oil. In this study, we investigated the feasibility of using transesterified sunflower oil as a plasticizer for ethyl cellulose (EC), a widely used hydrophobic biopolymer. The transesterification reaction, accelerated by the catalyst NaOH, resulted in the formation of short chemical compounds that improved the plasticity of EC films. The mechanical studies demonstrated a remarkable elongation break of approximately 94 %, setting a new record for this type of film. The plasticization process was confirmed through rheological and XRD studies, revealing a notable reduction in the elastic chain and crystallinity of the EC structure. The proposed process advances the state of the art in ethyl cellulose plasticization and stands out for its simplicity, cost-effectiveness, and environment-friendly approach. The synthesized films offer exciting possibilities for use in various applications including food packaging, transdermal drug delivery systems, and stretchable electronics.

Keywords

• Biomaterials
• Green synthesis
• Transesterification
• Ethyl cellulose
• Green plasticizers
• Supramolecular systems