A Study of Real-Time and Satellite Data of Atmospheric Pollutants during Agricultural Crop Residue Burning at a Downwind Site in the Indo-Gangetic Plain

Abstract

Crop residue burning emits a variety of air pollutants that drastically affect air quality, both locally and regionally. To study the impact of crop residue burning, in the present study, concentrations of particulate matter (PM2.5), trace gases (tropospheric ozone (O3), nitrogen oxides (NOx), carbon monoxide (CO), and volatile organic compounds (VOCs)) were recorded in Agra, a suburban downwind site. The study was conducted during the pre-harvest (15 September to 5 October 2021) and post-harvest periods (6 October to 10 November 2021). During the post-harvest period, PM2.5 concentrations were recorded to be three to four times higher than the NAAQ Standards (35 µg/m3), while O3 and VOC concentrations showed an increment of 16% and 30.4%, respectively. NOx and CO concentrations also showed higher levels (19.7 ± 7.5 ppb and 1498.5 ± 1077.5 ppb) during this period. Moderate resolution imaging spectroradiometer (MODIS), along with air mass backward trajectory analysis (HYSPLIT Model), were used to detect fire hotspots that suggested that the enhanced pollutant levels may be due to the burning of crop residue in agricultural fields over the northwest Indo-Gangetic Plain (NW-IGP). Field emission scanning electron microscopy with energy dispersive X-ray spectroscopy (FESEM-EDX) analysis showed high K concentrations during the post-harvest period, which may be attributed to crop residue burning or biomass combustion.

Keywords

• volatile organic compounds
• tropospheric ozone
• crop residue burning
• MODIS fire counts
• FESEM-EDX analysis