Acta Crystallographica Section E (Nov 2011)

2-(2-Bromoethyl)isoindoline-1,3-dione

  • Xiao-Qiang Sun,
  • Dong An,
  • Ying Shao

DOI
https://doi.org/10.1107/S1600536811039808
Journal volume & issue
Vol. 67, no. 11
pp. o2832 – o2832

Abstract

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The asymmetric unit of the title compound, C10H8BrNO2, contains three crystallographically independent molecules. Two of the N—C—C—Br side chains adopt anti conformations [torsion angles = −179.8 (5) and −179.4 (4)°] and the other is gauche [−66.5 (6)°]. The crystal structure features short Br...O [3.162 (5) Å] contacts, C—H...O hydrogen bonds and numerous π–π stacking interactions [centroid–centroid separations = 3.517 (4)–3.950 (4) Å].