Acta Crystallographica Section E (Jan 2009)

3,3′-Bis(4-chlorophenyl)-2,2′-(m-phenylenedioxy)diquinazolin-4(3H)-one

  • Hai-Zhou Yang,
  • Hai-Tao Gao,
  • Xu-Hong Yang

DOI
https://doi.org/10.1107/s1600536808040567
Journal volume & issue
Vol. 65, no. 1
pp. o59 – o60

Abstract

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In the title compound, C34H20Cl2N4O4, the two quinazoline heterocyclic systems and the adjacent chlorobenzene rings are not coplanar, but oriented at dihedral angles of 66.66 (13) and 52.48 (12)°, respectively. The quinazoline ring systems are nearly planar, with dihedral angles between the planes of the two rings of 5.43 (16) and 3.40 (14)°, and are oriented at dihedral angles of 79.73 (13) and 83.52 (13)° with respect to the adjacent benzene ring between them. Intermolecular C—H...O hydrogen bonds contribute to the stability of the structure. In addition, weak π–π stacking interactions [centroid-to-centroid distances = 3.872 (1) and 3.876 (1) Å] are observed in the crystal structure.