Synthesis of ethoxy dibenzooxaphosphorin oxides through palladium-catalyzed C(sp2)–H activation/C–O formation

Seohyun Shin; Dongjin Kang; Woo Hyung Jeon; Phil Ho Lee

doi:10.3762/bjoc.10.120

Beilstein Journal of Organic Chemistry (May 2014)

Synthesis of ethoxy dibenzooxaphosphorin oxides through palladium-catalyzed C(sp2)–H activation/C–O formation

Seohyun Shin,
Dongjin Kang,
Woo Hyung Jeon,
Phil Ho Lee

Affiliations

Seohyun Shin: Center for Catalytic Organic Reactions, National Creative Research Laboratory (NCRL), Chuncheon 200-701, Republic of Korea
Dongjin Kang: Center for Catalytic Organic Reactions, National Creative Research Laboratory (NCRL), Chuncheon 200-701, Republic of Korea
Woo Hyung Jeon: Center for Catalytic Organic Reactions, National Creative Research Laboratory (NCRL), Chuncheon 200-701, Republic of Korea
Phil Ho Lee: Center for Catalytic Organic Reactions, National Creative Research Laboratory (NCRL), Chuncheon 200-701, Republic of Korea

DOI: https://doi.org/10.3762/bjoc.10.120
Journal volume & issue: Vol. 10, no. 1
pp. 1220 – 1227

Abstract

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We report an efficient Pd-catalyzed C(sp2)–H activation/C–O bond formation for the synthesis of ethoxy dibenzooxaphosphorin oxides from 2-(aryl)arylphosphonic acid monoethyl esters under aerobic conditions.

Published in Beilstein Journal of Organic Chemistry

ISSN: 1860-5397 (Online)
Publisher: Beilstein-Institut
Country of publisher: Germany
LCC subjects: Science: Chemistry: Organic chemistry
Website: http://www.beilstein-journals.org/bjoc

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