Acta Crystallographica Section E (Dec 2009)

Methyl 4,5-diacetoxy-1-oxo-2-phenylperhydro-4,6-epoxycyclopenta[c]pyridine-7-carboxylate ethanol solvate

  • Victor N. Khrustalev,
  • Vladimir P. Zaytsev,
  • Inga K. Airiyan,
  • Atash V. Gurbanov,
  • Eugeniya V. Nikitina

DOI
https://doi.org/10.1107/S1600536809045528
Journal volume & issue
Vol. 65, no. 12
pp. o2981 – o2981

Abstract

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The title compound, the product of an acid-catalysed Wagner–Meerwein skeletal rearrangement, crystallizes as an ethanol monosolvate, C20H21NO8·C2H6O. The title molecule comprises a fused tricyclic system containing two five-membered rings (cyclopentane and tetrahydrofuran) in the usual envelope conformations and one six-membered ring (piperidinone) adopting a flattened twist–boat conformation.