Nature Communications (Dec 2017)

Electrical semiconduction modulated by light in a cobalt and naphthalene diimide metal-organic framework

  • Evandro Castaldelli,
  • K. D. G. Imalka Jayawardena,
  • David C. Cox,
  • Guy J. Clarkson,
  • Richard I. Walton,
  • Long Le-Quang,
  • Jerôme Chauvin,
  • S. Ravi P. Silva,
  • Grégoire Jean-François Demets

DOI
https://doi.org/10.1038/s41467-017-02215-7
Journal volume & issue
Vol. 8, no. 1
pp. 1 – 8

Abstract

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Photoactive and semiconducting metal-organic frameworks are desirable for electrical and photoelectrical devices, but remain rare. Here Demets and co-workers design a naphthalene diimide and cobalt based MOF with anisotropic electrical semiconductivity and a high responsivity of 2.5 × 105 A W−1.