Microplastic inhibits the sorption of trichloroethylene on modified biochar

Abstract

Biochar (BC) was used to remove trichloroethylene (TCE) from soil and water phases, and BC modification changed the sorption behavior of pollutants. Microplastics are emerging pollutants in the soil and water phases. Whether microplastics can affect the sorption of TCE by modified BC is not clear. Thus, batch sorption kinetics and isotherm experiments were conducted to elucidate the sorption of TCE on BC, and BC combined with polyethylene (PE) or polystyrene (PS). The results showed that HCl and NaOH modification increased TCE sorption on BC, while HNO3 modification inhibited TCE sorption on BC. When PE/PS and BC coexisted, the TCE sorption capacity decreased significantly on BC-CK + PE, BC-HCl + PE, BC-HNO3 + PE, BC-NaOH + PE, and BC-NaOH + PS, which was likely due to the preferential sorption of PE/PS on BC samples. We concluded that microplastics can change TCE sorption behavior and inhibit TCE sorption on BC samples. Thus, the interaction of BC and microplastics should be considered when BC is used for TCE removal in soil and water remediation. HIGHLIGHTS HCl and NaOH modification increased trichloroethylene (TCE) sorption on biochar.; HNO3 modification inhibited TCE sorption on biochar.; Microplastics could change TCE sorption behavior.; Polyethylene/polystyrene could preferentially adsorb onto biochar and inhibit TCE sorption by biochar samples.;

Keywords

• biochar
• microplastics
• modification
• sorption
• trichloroethylene (tce)